MetaCyc Reaction: 6.3.-.-

Superclasses: Reactions Classified By Conversion TypeSimple ReactionsChemical Reactions
Reactions Classified By SubstrateSmall-Molecule Reactions

EC Number: 6.3.-.-

The direction shown, i.e. which substrates are on the left and right sides, is in accordance with the direction in which it was curated.

Most BioCyc compounds have been protonated to a reference pH value of 7.3. Please see the PGDB Concepts Guide for more information.

Mass balance status: Balanced.

Enzyme Commission Primary Name: 6.3 -- Forming carbon-nitrogen bonds

Standard Gibbs Free Energy (ΔrG in kcal/mol): -19.395844Inferred by computational analysis [Latendresse13]

There is evidence that this reaction takes place in vitro in Arabidopsis thaliana, and (-)-JA-L-Val is a naturally occurring compound [Suza08, Staswick04, Fonseca09].


Fonseca09: Fonseca S, Chini A, Hamberg M, Adie B, Porzel A, Kramell R, Miersch O, Wasternack C, Solano R (2009). "(+)-7-iso-Jasmonoyl-L-isoleucine is the endogenous bioactive jasmonate." Nat Chem Biol 5(5);344-50. PMID: 19349968

Latendresse13: Latendresse M. (2013). "Computing Gibbs Free Energy of Compounds and Reactions in MetaCyc."

Staswick04: Staswick PE, Tiryaki I (2004). "The oxylipin signal jasmonic acid is activated by an enzyme that conjugates it to isoleucine in Arabidopsis." Plant Cell 16(8);2117-27. PMID: 15258265

Suza08: Suza WP, Staswick PE (2008). "The role of JAR1 in Jasmonoyl-L: -isoleucine production during Arabidopsis wound response." Planta 227(6);1221-32. PMID: 18247047

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Please cite the following article in publications resulting from the use of MetaCyc: Caspi et al, Nucleic Acids Research 42:D459-D471 2014
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