|Superclasses:||Reactions Classified By Conversion Type → Simple Reactions → Chemical Reactions|
|Reactions Classified By Substrate → Small-Molecule Reactions|
EC Number: 184.108.40.206
Enzymes and Genes:
|Mesorhizobium loti:||pyridoxal 4-dehydrogenase: pldh-t|
|Saccharomyces cerevisiae:||3-oxoacyl-[acyl-carrier-protein] reductase: OAR1|
In Pathway: vitamin B6 degradation
The direction shown, i.e. which substrates are on the left and right sides, is in accordance with the Enzyme Commission system.
Most BioCyc compounds have been protonated to a reference pH value of 7.3. Please see the PGDB Concepts Guide for more information.
Mass balance status: Balanced.
Enzyme Commission Primary Name: pyridoxal 4-dehydrogenase
Enzyme Commission Synonyms: pyridoxal dehydrogenase
Standard Gibbs Free Energy (ΔrG'° in kcal/mol): -20.377228 [Latendresse13]
Enzyme Commission Summary:
The enzyme acts on the hemiacetal form of the substrate.
Instance reactions of [a (3R)-3-hydroxyacyl-[acyl-carrier protein] + NADP+ ← a 3-oxoacyl-[acp] + NADPH + H+] (220.127.116.11/18.104.22.168/22.214.171.124):
i1: a (3R)-3-hydroxybutanoyl-[acp] + NADP+ ← an acetoacetyl-[acp] + NADPH + H+ (126.96.36.199/188.8.131.52/184.108.40.206)
i2: a (3R)-3-hydroxybehenoyl-[acp] + NADP+ = a 3-oxo-behenoyl-[acp] + NADPH + H+ (220.127.116.11)
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