|Superclasses:||Reactions Classified By Conversion Type → Simple Reactions → Chemical Reactions|
|Reactions Classified By Substrate → Small-Molecule Reactions|
EC Number: 18.104.22.168
Enzymes and Genes:
|Aggregatibacter actinomycetemcomitans :||GDP-4-keto-6-deoxy-D-mannose reductase
In Pathway: GDP-6-deoxy-D-talose biosynthesis
The reaction direction shown, that is, A + B ↔ C + D versus C + D ↔ A + B, is in accordance with the Enzyme Commission system.
Most BioCyc compounds have been protonated to a reference pH value of 7.3, and some reactions have been computationally balanced for hydrogen by adding free protons. Please see the PGDB Concepts Guide for more information.
Mass balance status: Balanced.
Enzyme Commission Primary Name: GDP-4-dehydro-D-rhamnose reductase
Enzyme Commission Synonyms: GDP-4-keto-6-deoxy-D-mannose reductase, GDP-4-keto-D-rhamnose reductase, guanosine diphosphate-4-keto-D-rhamnose reductase, GDP-6-deoxy-D-mannose:NAD(P)+ 4-oxidoreductase, GDP-6-deoxy-α-D-mannose:NAD(P)+ 4-oxidoreductase
Standard Gibbs Free Energy (ΔrG'° in kcal/mol): -10.649292 [Latendresse13]
Enzyme Commission Summary:
The enzyme, which operates in the opposite direction to that shown, forms a mixture of GDP-α-D-rhamnose and its C-4 epimer, GDP-6-deoxy-α-D-talose. cf. EC 22.214.171.1241, GDP-4-dehydro-6-deoxy-D-mannose reductase and EC 126.96.36.199, GDP-6-deoxy-D-talose 4-dehydrogenase.
Unification Links: KEGG:R03398
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