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MetaCyc Compound: all-trans-decaprenyl diphosphate

Superclasses: a lipid an isoprenoid an isoprenoid phosphate an isoprenoid diphosphate an all-trans-polyisoprenyl diphosphate

Summary:
For polyisoprenols and polyisoprenyl phosphates nomenclature, see an isoprenoid.

Chemical Formula: C50H81O7P2

Molecular Weight: 856.13 Daltons

Monoisotopic Molecular Weight: 858.5692280710999 Daltons

all-<i>trans</i>-decaprenyl diphosphate compound structure

SMILES: CC(=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCOP(=O)([O-])OP(=O)([O-])[O-])C

InChI: InChI=1S/C50H84O7P2/c1-41(2)21-12-22-42(3)23-13-24-43(4)25-14-26-44(5)27-15-28-45(6)29-16-30-46(7)31-17-32-47(8)33-18-34-48(9)35-19-36-49(10)37-20-38-50(11)39-40-56-59(54,55)57-58(51,52)53/h21,23,25,27,29,31,33,35,37,39H,12-20,22,24,26,28,30,32,34,36,38,40H2,1-11H3,(H,54,55)(H2,51,52,53)/p-3/b42-23+,43-25+,44-27+,45-29+,46-31+,47-33+,48-35+,49-37+,50-39+

InChIKey: InChIKey=FSCYHDCTHRVSKN-CMVHWAPMSA-K

Unification Links: ChEBI:60721 , HMDB:HMDB59616 , KEGG:C17432 , PubChem:25245574

Standard Gibbs Free Energy of Change Formation (ΔfG in kcal/mol): 642.7823 Inferred by computational analysis [Latendresse13]

Reactions known to consume the compound:

menaquinol-10 biosynthesis :
all-trans-decaprenyl diphosphate + 1,4-dihydroxy-2-naphthoate + H+ → CO2 + demethylmenaquinol-10 + diphosphate

ubiquinol-10 biosynthesis (eukaryotic) , ubiquinol-10 biosynthesis (prokaryotic) :
all-trans-decaprenyl diphosphate + 4-hydroxybenzoate → 3-decaprenyl-4-hydroxybenzoate + diphosphate

Reactions known to produce the compound:

all-trans-decaprenyl diphosphate biosynthesis , ubiquinol-10 biosynthesis (eukaryotic) :
(2E,6E)-farnesyl diphosphate + 7 isopentenyl diphosphate → all-trans-decaprenyl diphosphate + 7 diphosphate

In Reactions of unknown directionality:

Not in pathways:
an all-trans-polyisoprenyl diphosphate + 1,4-dihydroxy-2-naphthoate + H+ = CO2 + a demethylmenaquinol + diphosphate

Not in pathways:
an isoprenoid diphosphate + 4-hydroxybenzoate = a 4-hydroxy-3-polyprenylbenzoate + diphosphate


References

Latendresse13: Latendresse M. (2013). "Computing Gibbs Free Energy of Compounds and Reactions in MetaCyc."


Report Errors or Provide Feedback
Please cite the following article in publications resulting from the use of MetaCyc: Caspi et al, Nucleic Acids Research 42:D459-D471 2014
Page generated by SRI International Pathway Tools version 19.0 on Tue Mar 31, 2015, BIOCYC13B.