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Escherichia coli K-12 substr. MG1655 Compound Class: a plant arabinogalactan type II

Synonyms: type I AG, arabino-3,6-galactan

Superclasses: all carbohydrates a carbohydrate a glycan a polysaccharide an arabinogalactan a plant arabinogalactan

Summary:
Arabinogalactans (AGs) are widely spread throughout the plant kingdom. Many edible and inedible plants are rich sources of these polysaccharides. AGs are associated with the pectin cell-wall component by physical bonds, and some of them are covalently linked to the complex pectin molecule as neutral side chains [Ebringerova05].

AGs occur in two structurally different forms described as type I and type II.

AG type II, known as arabino-3,6-galactan, has a (1→3)-β-D-Galp backbone heavily substituted at position 6 by mono- and oligosaccharide side chains composed of arabinosyl and galactosyl units. It is more widespread than the AG type I and occurs in cell walls of dicots and cereals often linked to proteins (known as arabinogalactan proteins). AG type II, along with galactomannans and cellulose, comprises the predominating polysaccharides of green arabica coffee beans[Fischer01]. In some case type II AGt contains a small amount of β-glucuronate.

AG type II occurs as minor, water-soluble components in softwoods. It is very abundant in the wood of larch trees (members of the genus Larix) - certain parts of the western larch (Larix occidentalis) contain up to 35% AG [Whistler93]. However, larch AG type II is located in the lumen of the tracheids and ray cells, and is thus not a cell-wall component and by definition, not part of the hemicellulose of these trees.

SMILES: C(O)C9(C(O)C(O)C(OCC8(C(O)C(O)C(OCC7(C(O)C(O)C(OCC6(C(O)C(O)C(OCC5(C(O)C(O[R1])C(O)C(OC4(C(O)C(OC3(C(O)C(OC1(C(O)C(O[R2])OC(CO)C(O)1))OC(COC2(OC(CO)C(O)C(O)2))C(O)3))OC(CO)C(O)4))O5))O6))O7))O8))O9)

Credits:
Created 08-Jun-2011 by Caspi R , SRI International


References

Ebringerova05: Ebringerova, A., Hromadkova, Z., Heinze, T. (2005). "Hemicellulose." Adv Polym Sci 186:1-67.

Fischer01: Fischer M, Reimann S, Trovato V, Redgwell RJ (2001). "Polysaccharides of green Arabica and Robusta coffee beans." Carbohydr Res 330(1);93-101. PMID: 11217967

Habibi04: Habibi Y, Mahrouz M, Marais MF, Vignon MR (2004). "An arabinogalactan from the skin of Opuntia ficus-indica prickly pear fruits." Carbohydr Res 339(6);1201-5. PMID: 15063212

Whistler93: Whistler, R. L. (1993). "Larch Arabinogalactan." In Industrial Gums, Polysaccharides and Their Derivatives. eds. BeMiller J. and Whistler, R., Academic Press, San Diego.


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Please cite the following article in publications resulting from the use of EcoCyc: Nucleic Acids Research 41:D605-12 2013
Page generated by SRI International Pathway Tools version 18.5 on Thu Nov 27, 2014, biocyc13.